The big show will be airing on May, 31st, 2009 at 9PM ET and will be hosted by Andy Samberg. As many may already know Twilight and it's cast members are up for the most nominations! Voting is free and easy! Just head over to MTV.com, log in and cast your votes for your favorites in all of the categories before Wednesday, May 27, but remember, voting for Best Movie will remain open right up until…